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The edge length of a face centered cubic cell of an ionic substance is 508 pm. If the radius of the cation is 110 pm, the radius of the anion is
Copper crystallises in fcc with a unit cell length of 361 pm.What is the radius of copper atom?
For fcc unit cell, 4r =\(\sqrt{2}a\)
r = \(\frac{\sqrt{2} \times 361}{4}\) = 127pm
In a compound, atoms of element Y form ccp lattice and those of element X occupy 2/3rd of tetrahedral voids. The formula of the compound will be
From the given data, we have
Number of Y atoms in a unit cell = 4
Number of X atoms in a unit cell = 8 ∴ \(\frac{2}{3}\) = \(\frac{16}{3}\)
From the above we get the formula of the compound as X16/3Y4 or X4Y3
A metal crystallizes with a face-centered cubic lattice. The edge length of the unit cell is 408 pm. The diameter of the metal atom is :
A solid compound XY has NaCl structure. If the radius of the cation is 100 pm, the radius of the anion (Y–) will be :
Among the following which one has the highest cation to anion size ratio?
\(\frac{M^{+}}{X^{-}}\) is highest in CsF.
∴ correct choice : (c)
AB; crystallizes in a body centred cubic lattice with edge length ‘a’ equal to 387 pm. The distance between two oppositely charged ions in the lattice is :
With which one of the following elements silicon should be doped so as to give p-type of semiconductor ?
The semiconductors formed by the introduction of impurity atoms containing one electron less than the parent atoms of insulators are termed as p-type semiconductors. Therefore silicon containing 14 electrons is to be doped with boron containing 13 electrons to give a p-type semi-conductor.