Stainless steel contains iron and
In which of the following metallic bond is strongest ?
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Solution
Strength of metallic bond directly depends on the number of unpaired electrons. More is number of unpaired electrons stronger is metallic bond. Hence,metallic bond is strongest in Cr having maximum of 6 unpaired electrons among the given options, i.e., Sc (1 unpaired electron), V (3 unpaired electrons) and Fe (4 unpaired electrons).
The liquified metal expanding on solidification is
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Solution
Among the given options Ga is the only liquid metal which expands on solidification.It has an unusual structure. Each metal atom has one close neighbour at a distance of 2.43 Å, and six more neighbours at distances within range of 2.70 Å to 2.79 Å. Due to this structure it exists as discrete diatomic molecules rather than a metallic structure in crystal form which is less dense than its liquid form. As its solid form is heated to 30°C,due to weak metallic bonds this unusual structure no longer exists and melts to liquid. This property is unique to Ga, Ge and Bi.
The number of unpaired electrons in gaseous species of Mn3+, Cr3+ and V3+ respectively are.
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Solution
In first transition series, the melting point of Mn is low because
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Solution
Due to d5 configuration, Mn has exactly half filled d-orbitals. As a result the electronic configuration is stable means 3d electrons are more tightly held by the nucleus and this reduces the delocalization of electrons resulting in weaker metallic bonding.
Percentage of silver in German silver is :
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Solution
German silver is
Cu = 25 -50%
Zn = 25 -35%
Ni = 10- 35%
Used as utensils, resistance wire.
Which of the following configuration is correct for iron ?
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Solution
Configuration of Fe ( Z = 26)
1s2, 2s2, 2p6, 3s2, 3p6, 3d6, 4s2
Which of the following element is not a member of transition elements ?
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Solution
Cerium (Ce) belongs to lanthanide series and is member of inner-transition metals.
The transition metal with least atomic number is :
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Solution
Zirconium (Z = 40).
Which of the following metal ions is not coloured?
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Solution
The ion having all electrons paired is not coloured.
(a) Ti3+ = 1s2, 2s2, 2p6, 3s2, 3p6, 3d1,4s0
(b) Fe3+ = 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s0
(c) V3+ = 1s2, 2s2, 2p6, 3s2, 3p6, 3d2, 4s0
(d) Cu+ = 1s2, 2s2, 2p6, 3s2, 3p6, 3d10,4s0
∵ Only Cu+does not have any unpaired electron, it is not coloured.