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The emf of the cell Ni | Ni2+(1.0 M)| |Au3+(1.0M)| Au is[Given E° Ni2+/ Ni = – 0.25 V and E° Au3+/ Au = +1.5 V]
The volume of oxygen gas liberated at NTP by passing a current of 9650 coulombs through acidified water is :
A current of 96500 coulombs liberate 1 mole of O2.
⇒96500 C liberates = 22.4 L of O2 at NTP
⇒9650 C liberates = 2.24 L of O2 at NTP
The same amount of electricity was passed through two cells containing molten Al2O3 and molten NaCl. If 1.8 g of Al were liberated in one cell, the amount of Na liberated in other cell is:
In a cell that utilises the reaction Zn(s) + 2H+(aq) ⟶ Zn2+(aq) + H2(g) addition of H2SO4 to cathode compartment, will
The standard e.m.f. of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25°C. The equilibrium constant of the reaction would be (Given F = 96500 C mol-1; R = 8.314 J K-1 mol-1)
On passing electric current of one ampere for 16 min and 5 sec through one litre solution of CuCl2, all copper of solution was deposited at cathode. The strength of CuCl2 solution was (molar mass of Cu = 63.5, Faraday constant = 96500 C/mol):
In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. The reason is
Cu+(aq) is unstable in solution and undergoes simultaneous oxidation and reduction according to the reaction :
2Cu+(aq) ⇌ 2Cu2+(aq) + Cu(s)
choose correct Eº forgiven reaction if Eº Cu2+/Cu = 0.34 V and Eº Cu2+/Cu+ = 0.15 V