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How many bonding electronpairs are there in white phosphorus ?
∵ Each P-atom forms 3 bonds. Thus it has 3 bond pairs of electrons.
Ammonia on reaction with hypochlorite anion can form :
N2H4 and NH4Cl are obtained by reaction of ammonia with hypochlorite anion.
3NH3 + NaOCl → N2H4NHCl + NaOH
Chlorine upon reaction with NaOH in cold yields:
\(2NaOH + Cl_{2} \overset{cold}{\rightarrow} NaCl + \underset{Sod. hypo-chlorite}{NaClO}+ H_{2}O\)
In Haber’s process for the manufacture of 3NH:
In Haber’s process for manufacture of NH3, finely divided iron is used as catalyst and molybdenum is used as catalytic promoter
\(N_{2}(g)+3H_{2}(g) \begin{matrix} Fe + Mo{°}\\ \;----\rightarrow \\ 800K,HighP\end{matrix} 2NH(g)\)
NH3 gas can be dried by?
NH3 gas can be dried by CaO (calcium oxide orquicklime).
NH4ClO4 + HNO3(dil.) → HClO4[X] [X]\(\overset{\Delta }{\rightarrow}\)Y(g)
[X] and [Y] are respectively –NH4ClO4+ HNO3 → HClO4 + NH4NO3
NH4NO3 \(\overset{\Delta }{\rightarrow}\) N2O + 2H2O
The most efficient agent for the absorption of SO3 is :
Most efficient agent for the absorption of SO3 is 98% H2SO4. They form oleum.
SO3 + H2S2O7(oleum)
Sulpher trioxide is not directly absorbed in water to form sulphuric acid because it forms dense fog of sulphuric acid.
Nitrogen reacts with calcium and carbon to give –
Most acidic oxide among the following is –
Oxide in which central atom has higher charge and more electronegativity is more acidic, i.e. N2O5 > N2O4 > P2O5> As2O3.
Concentrated sulphuric acid is always diluted by adding
concentrated sulphuric acid is always diluted by adding acid to water because the process of mixing generates a lot of heat. If we add water to acid due to generation of large amount of heat acid may spill over to its surroundings.