How many bridging oxygen atoms are present in P4O10?
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Solution
Which one of the following compounds is a peroxide ?
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Solution
Oxidation states of Pin H4P2O5, H4P2O6, and H4P2O7,are respectively:
The correct order of increasing bond angles in the following species are :
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Solution
The correct order of increasing bond angle is
Cl2O < \(ClO_{2}^{-}\) < ClO2
* In \(ClO_{2}^{-}\) there are 2 lone pairs of electrons present on the central chlorine atom. Therefore the bond angle in \(ClO_{2}^{-}\) is less than 118° which is the bond angle in ClO2 which has less number of electrons on central chlorine atom.
Among the following which is the strongest oxidising agent?
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Solution
Since all the halogens have a strong tendency to accept electrons. Therefore halogens act as strong oxidising agents and their oxidising power decreases from fluorine to iodine.
In the case of alkali metals, the covalent character decreases in the order:
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Solution
MI > MBr > MCl > MF. As the size of the anion decreases covalent character also decreases.
Which one of the following arrangements does not give the correct picture of the trends indicated against it ?
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Solution
(b, c) From the given options we find option (a) is correct.The oxidising power of halogens follow the order F2> Cl2> Br2> I2. Option(b)is incorrect because it in not the correct order of electron gain enthalpy of halogens.The correct order is Cl2> F2> Br2 > I2. The low value of F2 than Cl2 is due to its small size.Option(c) is incorrect. The correct order of bond dissociation energies of halogens is Cl2> Br2> F2> I2.Option(d) is correct. It is the correct order of electronegativity values of halogens. Thus option(b)and (c) are incorrect.
Which one of the following orders correctly represents the increasing acid strengths of the given acids?
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Solution
\(\underset{+1}{HOCl}< \underset{+3}{HOClO}< \underset{+5}{HOClO_{2}}< \underset{+7}{HOClO_{3}}\)
In case of oxyacids of similar element as the oxidation number of the central atom increases, strength of acid also increases.
The species not containing peroxide ions is :
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Solution
PbO2 does not contain peroxide ion. It is lead dioxide.
The formation of \(O_{2}^{+}[ptF_{6}]^{-}\) is the basis for the formation of xenon fluorides. This is because
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Solution
(i) The first ionization energy of xenon (1, 170 kJ mol–1)is quite close to that of dioxygen (1,180 kJ mol–1).(ii)The molecular diameters of xenon and dioxygen are almost identical.Based on the above similarities Barlett (who prepared \(O_{2}^{+}[ptF_{6}]^{-}\)compound) suggested that since oxygen combines with PtF6, so xenon should also form similar compound with PtF6.