Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is :
Amongst the elements with following electronic configurations, which one of them may have the highest ionization energy?
-
Ne [3s2 3p2]
-
Ar [3d10 4s2 4p3 ]
-
Ne [3s2 3p1]
-
Ne [3s2 3p3]
-
Solution
The smaller the atomic size, larger is the value of ionisation potential. Further the atoms having half filled or fully filled orbitals are comparitively more stable,hence more energy is required to remove the electron from such atoms.
In which of the following electronic configuration an atom has the lowest ionisation enthalpy?
-
1s2 2s2 2p3
-
1s2 2s2 2p5 3s1
-
1s2 2s2 2p6
-
1s2 2s2 2p5
One of the characteristic properties of non-metals is that they
-
Are reducing agents
-
Form basic oxides
-
Form cations by electron gain
-
Are electronegative
-
Solution
Non metals form oxides with oxygen and thus reduce oxides of metals behaving as reducing agents.
Which of the following sets has strongest tendency to form anions ?
-
Ga, In, Tl
-
Na, Mg, Al
-
N, O, F
-
V,Cr, Mn
-
Solution
N, O and F (p-block elements) are highly electronegative non metals and will have the strongest tendency to form anions by gaining electrons from metal atoms.
Which of the following is not the correct order for the stated property ?
-
Ba > Sr > Mg; atomic radius
-
F> O > N :first ionization enthalpy
-
Cl > F >I; electron affinity
-
O> Se > Te; electronegativity
-
Solution
On moving along the period, ionization enthalpy increases.
In second period, the order of ionization enthalpy should be as follows : F > O > N But N has half-filled structure, therefore, it is more stable than O. That’s why its ionization enthalpy is higher than O. Thus, the correct order of IE is F > N >O.
An element of atomic weight 40 has 2, 8, 8, 2 as the electronic configuration. Which one of the following statements regarding this element is not correct
-
it belongs to II group of the periodic table
-
it has 20 neutrons
-
the formula of its oxide is MO2
-
it belongs to 4th period of the periodic table
-
Solution
Its valency is 2. So it will form MO type compound.
Which transition involves maximum amount of energy?
-
M(g)⟶ M(g) + e
-
M(g)⟶ M(g) + 2e
-
M(g)⟶ M2+(g) + e
-
M2+(g)⟶ M3+(g) + e
-
Solution
The energy involved is ionisation energy (I.E.). Further the 3rd ionisation energy will be greater than the 2nd and 1st.
Which of the following sequence correctly represents the decreasing acidic nature of oxides ?
-
Li2O >BeO > B2O3 > CO2 > N2O3
-
N2O3 > CO2> B2O3 > BeO > Li2O
-
CO2 > N2O3 > B2O3 > BeO > Li2O
-
B2O3 > CO2 > N2O3 > Li2O > BeO
-
Solution
On passing from left to right in a period acidic character of the normal oxides of the elements increases with increase in electronegativity.
The outermost electronic configuration of the most electronegative element is
-
ns2 np3
-
ns2 np4
-
ns2 np5
-
ns2 np6
-
Solution
Halogens are most electronegative.