Na+,Mg2+,Al3+ and Si4+ ions are isoelectronic. The value of ionic radii of these ions would be in the order :
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Solution
Species Na+Mg2+Al3+Si4+
Protons 11 12 13 14
Electrons 10 10 10 10
Size of isoelectronic cations decreases with increase in magnitude of nuclear charge
∴Order of decreasing size is Na+>Mg2+>Al3+>Si4+
Which is a metalloid ?
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Solution
Arsenic is the only metalloid among the given options.Its small amounts are even very harmful for humans
Sequence of acidic character is
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Solution
The acidic character of non metal oxides increases acrossa period from left to right and decreases down a group.So, acidic character will follow the order:oxide of nitrogen > oxides of sulfur > oxides of carbon.Among oxides of carbon acidic character increases withthe oxidation number of carbon. So, +4CO 2 is moreacidic than CO. Hence thesequence of acidic characteris N2O5> SO2> CO2> CO
The ionization energy of nitrogen atom is more than that of oxygen atom because of
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Solution
According to the general trend of I.E. in a period,it is expected that oxygen atom has higher I.E. than nitrogenatom but nitrogen atom has more stable half filled p-orbitals due to which it has higher I.E. than oxygenatom.
Which one of the following is smallest in size ?
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Solution
They are isoelectronic species.
N3– O2- Na+ F-
No. of electrons 10 10 10 10
No. of protons 7 8 11 9
∴Attractive forces are highest in Na+.
∴Na+ is smallest in size.
Which one has least ionisation potential?
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Solution
Ionisation potential increases while moving in a period.
Group V VI VII VIII
Element N O F Ne
Oxygen (group 6) has low ionisation potential than N(group 5) because of stable configuration of nitrogen(half filled p-orbital)
The ionisation potential order for which set is correct?
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Solution
While moving down in a group, effective nuclear attraction decreases due to addition of new orbits. As a result ionisation potential decreases. Hence, the correct order is Li > K > Cs.
Which one of the following has largest size?
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Solution
While moving down in a group, effective nuclear attraction decreases due to addition of new orbits. As a result ionisation potential decreases. Hence, the correct order is Li > K > Cs.
The correct order of ionization energies is
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Solution
A cation is always smaller in size as compared to corresponding neutral atom. Greater the magnitude of charge, smaller will be size of ion. Following is the correct order of decreasing size Al3+< Al2+< Al+< Al. ∴Al has largest size
Amphoteric-oxide combinations are in
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Solution
Basicity of oxides decreases in a period and increases in a group.
∴SnO2, Al2O3 and ZnO are amphoteric oxides.