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Which of the following alcohols gives the best yield of dialkyl ether on being heated with at race of sulphuric acid?
1-pentanol Primary alcohols readily form ether when heated with conc.H2SO4.
Methylphenyl ether can be obtained by reacting
\(C_{6}H_{6}O^{-} + CH_{3}I \rightarrow C_{6}H_{5}OCH_{3} + I^{-}\)
Diethyl ether on heating with conc. HI gives two moles of
\(C_{2}H_{5}OC_{2}H_{5} + 2HI \overset{\Delta }{\rightarrow} 2C_{2}H_{5}I + H_{2}O\)
The compound that undergoes dehydration very easily is
The ease of dehydration of alcohols is 3° > 2° >1°.Tertiary alcohols undergo dehydration more easily than primary and secondary alcohols.
Etherates are
The ether that undergoes electrophilic substitution reactions is
Only alkylaryl ethers e.g., C6H5OCH3 undergoes electrophilic substitution reactions.
In the following reaction
\(C_{2}H_{5}OC_{2}H_{5} + 4[H] \overset{Red P + HI}{\rightarrow} 2X + H_{2}O\) , X is