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A mass of ideal gas at pressure P is expanded isothermally to four times the original volume and then slowly compressed adiabatically to its original volume. Assuming γ to be 1.5, the new pressure of the gas is
Let P and V be the initial pressure and volume of ideal gas. After isothermal expansion, pressure is P/4. So volume is 4 V.
Let P1 be the pressure after adiabatic compression.
Then
P1Vγ=(P / 4)(4 V)γ
P1=(P / 4)(4)3/2=2 P
A system changes from the state (P1, V1) to (P2, V2) as shown in the figure. What is the work done by the system?
\(W=\frac{(1\times 10^{5}+6\times 10^{5}) (5-1)}{2}\)
\(=\frac{6\times 10^{5}\times 4}{2}=12\times 10^{5}\) joule
A refrigerator works between 0°C and 27°C. Heat is to be removed from the refrigerated space at the rate of 50 k cal/minute, the power of the motor of the refrigerator is
\(\frac{T_{2}}{T_{1}-T_{2}}=\frac{Q_{2}}{W}\)
\(\frac{273}{300-273}=\frac{50,000}{W}\)
\(W=\frac{27\times 50,000}{273}\)cal/min
\(p=\frac{W}{t}=\frac{4.2\times 27\times 50,000}{60\times 273}\)Joule/sec
= 346 watt = 0.346 kW
A perfect gas goes from a state A to another state B by absorbing 8 × 105 J of heat and doing 6.5 × 105 J of external work. It is now transferred between the same two states in another process in which it absorbs 105 J of heat. In these condprocess
dU = dQ - dW = (8 × 105 - 6.5 × 105) = 1.5 × 105J
dW = dQ - dU = 105 - 1.5 × 105 = -0.5 × 105J – vesign indicates that work done on the gas is 0.5 × 105J.
The temperature of 5 moles of a gas which was held at constant volume was changed from 100° to 120°C. The change in the internal energy of the gas was found to be 80 joule,the total heat capacity of the gas at constant volume will be equal to
dU=nCvdt or 80=5×Cv(120-100)
Cv= 4.0 joule/K